CN202881672U - 一种采用超临界流体静态染色的装置
文章推薦指數: 80 %
本实用新型公开一种采用超临界流体静态染色的装置,所述装置包括上染系统和超临界流体静态显色固色系统;所述上染系统包括上染装置及与所述上染装置连接的染料池; ...
CN202881672U-一种采用超临界流体静态染色的装置
-GooglePatents
一种采用超临界流体静态染色的装置
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Publicationnumber
CN202881672U
CN202881672U
CN201220448514XU
CN201220448514U
CN202881672U
CN202881672U
CN202881672U
CN202881672U
CN201220448514XU
CN201220448514XU
CN201220448514XU
CN201220448514U
CN201220448514U
CN201220448514U
CN202881672U
CN202881672U
CN202881672U
Authority
CN
China
Priorartkeywords
supercriticalfluid
static
fixation
dye
dying
Priorartdate
2012-09-04
Legalstatus(Thelegalstatusisanassumptionandisnotalegalconclusion.Googlehasnotperformedalegalanalysisandmakesnorepresentationastotheaccuracyofthestatuslisted.)
Expired-Lifetime
Applicationnumber
CN201220448514XU
Otherlanguages
English(en)
Inventor
郭晓洁
包桂莲
CurrentAssignee(Thelistedassigneesmaybeinaccurate.Googlehasnotperformedalegalanalysisandmakesnorepresentationorwarrantyastotheaccuracyofthelist.)
GUANGDONGEXCELLENTANHYDROUSDYEINGPRINTINGTECHNOLOGYCOLTD
OriginalAssignee
GUANGDONGEXCELLENTANHYDROUSDYEINGPRINTINGTECHNOLOGYCOLTD
Prioritydate(Theprioritydateisanassumptionandisnotalegalconclusion.Googlehasnotperformedalegalanalysisandmakesnorepresentationastotheaccuracyofthedatelisted.)
2012-09-04
Filingdate
2012-09-04
Publicationdate
2013-04-17
2012-09-04
ApplicationfiledbyGUANGDONGEXCELLENTANHYDROUSDYEINGPRINTINGTECHNOLOGYCOLTD
filed
Critical
GUANGDONGEXCELLENTANHYDROUSDYEINGPRINTINGTECHNOLOGYCOLTD
2012-09-04
PrioritytoCN201220448514XU
priority
Critical
patent/CN202881672U/zh
2013-04-17
Applicationgranted
granted
Critical
2013-04-17
PublicationofCN202881672U
publication
Critical
patent/CN202881672U/zh
2022-09-04
Anticipatedexpiration
legal-status
Critical
Status
Expired-Lifetime
legal-status
Critical
Current
Links
Espacenet
GlobalDossier
Discuss
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0.000
description
9
229910001868
water
Inorganicmaterials
0.000
description
9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N
ethanol
Chemicalcompound
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CCO
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0.000
description
4
239000007789
gas
Substances
0.000
description
4
238000004519
manufacturingprocess
Methods
0.000
description
4
OKKJLVBELUTLKV-UHFFFAOYSA-N
methanol
Chemicalcompound
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OKKJLVBELUTLKV-UHFFFAOYSA-N
0.000
description
4
IJGRMHOSHXDMSA-UHFFFAOYSA-N
nitrogen
Chemicalcompound
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ammonia
Chemicalcompound
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Chemicalcompound
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ethene
Chemicalcompound
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Inorganicmaterials
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description
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Substances
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description
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Methods
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Substances
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propane
Chemicalcompound
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Substances
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Chemicalgroup
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[H]C([H])([H])C([H])([*:1])C([H])([H])[*:2]
0.000
description
2
239000000985
reactivedye
Substances
0.000
description
2
238000002791
soaking
Methods
0.000
description
2
NINIDFKCEFEMDL-UHFFFAOYSA-N
sulfur
Chemicalcompound
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D—TEXTILES;PAPER
D06—TREATMENTOFTEXTILESORTHELIKE;LAUNDERING;FLEXIBLEMATERIALSNOTOTHERWISEPROVIDEDFOR
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D06B19/0005—Fixingofchemicals,e.g.dyestuffs,ontextilematerials
D—TEXTILES;PAPER
D06—TREATMENTOFTEXTILESORTHELIKE;LAUNDERING;FLEXIBLEMATERIALSNOTOTHERWISEPROVIDEDFOR
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D06B1/02—Applyingliquids,gasesorvapoursontotextilematerialstoeffecttreatment,e.g.washing,dyeing,bleaching,sizingorimpregnatingbysprayingorprojecting
D—TEXTILES;PAPER
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Abstract
本实用新型公开一种采用超临界流体静态染色的装置,所述装置包括上染系统和超临界流体静态显色固色系统;所述上染系统包括上染装置及与所述上染装置连接的染料池;所述超临界流体静态显色固色系统包括超临界流体供应装置、与所述超临界流体供应装置连接的一台或一台以上并联的超临界流体显色固色釜、与所述超临界流体显色固色釜连接的超临界流体回收装置。
本实用新型所述超临界流体静态染色装置,在显色固色过程中,超临界流体处于静止状态,省去了复杂的超临界流体循环流动设备,使得设备的投入和能量消耗大大减小。
同时,显色固色过程超临界流体处于静止状态,不会发生染料迁移现象,染色质量容易控制,更换染色颜色时,不必清洗染色系统。
Description
一种采用超临界流体静态染色的装置
技术领域
[0001] 本实用新型涉及一种采用超临界流体对纤维、纱线和织物等进行染色的装置,尤其是一种采用超临界流体对纤维、纱线和织物等进行静态染色的装置。
背景技术
[0002] 传统的织物染色多数采用水染色工艺,而水染色工艺一方面需要消耗大量的水资源,另一方面产生的大量废水严重地污染了环境。
因此,印染行业的水资源消耗以及废水排放问题已经严重制约了国家可持续发展战略以及印染行业的发展,并且严重地影响到了人民的生活质量。
[0003] 研究及开发新型节水环保的染色技术成为国家、行业及企业的迫切需要,经过科技人员的不懈努力,近年来,先后开发了一些新型的无水或少水染色技术,但由于生产成本、产品质量控制以及生产效率的原因,目前仍然没有一种能够完全取代水染色的方法获得广泛应用。
[0004] 近年来,超临界流体印染技术的研究逐渐引起人们的关注。
超临界流体染色技术是利用某种流体在超临界状态下对纤维具有较强的溶胀作用以及对某些染料具有较好的溶解性能,可以在无水状态下使得染料快速上染于纤维,从而实现对纤维染色,是一种新型环保的无水染色技术。
[0005] 然而,由于大部分流体的超临界状态都处于高压高温状态,使得研制用于生产的高压超临界染色装置面临很多技术上的难题且造价也比较昂贵;同时,由于整个系统设备处于高压密封状态,使得在染色过程中进行染色质量监控相当困难;另外,由于溶解了染料的超临界流体在系统中处于流动状态,使得残留于系统设备、管路、阀门中的染料清洗比较困难,很难适应生产中经常更换染色颜色的需求。
[0006] 因此,开发一种既能保持超临界流体在无水条件下快速染色的优点,同时又具有染色工艺简单、染色质量容易控制、染色系统不用清洗,设备投入低廉的超临界流体染色工艺及生产装置,是当前印染行业的迫切期待。
发明内容
[0007] 本实用新型的目的在于克服现有技术的不足之处而提供一种染色工艺简单、染色质量容易控制、染色系统不用清洗、设备投入低廉的超临界流体静态染色装置。
[0008]为实现上述目的,本实用新型的采取的技术方案为:一种采用超临界流体静态染色方法的装置,所述装置包括上染系统和超临界流体静态显色固色系统;
[0009] 所述上染系统包括上染装置及与所述上染装置连接的染料池;
[0010] 所述超临界流体静态显色固色系统包括超临界流体供应装置、与所述超临界流体供应装置连接的一台或一台以上并联的超临界流体显色固色釜、与所述超临界流体显色固色釜连接的超临界流体回收装置。
[0011] 作为上述技术方案的改进,所述超临界流体供应装置包括流体储罐、与所述流体储罐连接的流体加压设备及加热或冷却设备。
[0012] 作为上述技术方案的改进,所述流体加压设备为压缩机或高压泵;所述加热或冷却设备为换热器。
[0013] 作为上述技术方案的改进,所述超临界流体显色固色釜包括釜体、设于釜体上部的釜盖密封装置、内置于釜体中的待染物固定装置、设于釜体上的超临界流体进口和超临界流体出口以及用于保持釜体温度的保温夹套。
[0014] 作为上述技术方案的改进,所述装置还包括用于对超临界流体的压力、温度、流量和液位进行控制和记录的电气仪表控制系统。
[0015] 使用上述所述装置进行超临界流体静态染色时,可采用如下步骤:
[0016] (I)上染:将待染物置于上染系统的上染装置,将燃料池中的染料加入到上染装置中,对待染物进行上染;
[0017] (2)超临界流体静态显色固色:将步骤(I)中上染后的待染物放入超临界流体显色固色釜中,从超临界流体供应装置输出超临界流体至超临界流体显色固色釜,在超临界流体显色固色釜中,将待染物在静态超临界流体中进行显色及固色;
[0018] (3)显色及固色结束后,排除系统压力,回收超临界流体到超临界回收装置中,打开超临界流体显色固色釜,取出待染物即可。
[0019] 所述步骤(I)中,待染物在常温、常压状态下,采用浸泡、喷涂、浸轧或转移的方式使染料上染。
所述待染物经过步骤(I)的上染过程后带液率为犷90%。
所述步骤(I)上染过程中采用的染料选自直接染料、酸性染料、活性染料、阳离子染料、分散染料、还原染料、偶氮染料、硫化染料以及不含助剂的染料原粉中的至少一种。
[0020] 所述步骤(2)中的超临界流体选自水、氮气、二氧化碳、乙烧、乙烯、丙烧、丙烯、氨、甲醇、乙醇中的至少一种。
所述步骤(2)中待染物在超临界流体显色固色釜中静态染色的压力为l〜60MPa,温度为(T220°C。
所述步骤(2)中,在超临界流体显色固色釜中,待染物在静态超临界流体中进行显色及固色的时间为0.5^5小时。
[0021] 上述所述待染物为纤维、纱线或织物;所述纤维包括天然纤维、合成纤维及混纺纤维。
[0022] 本实用新型所述采用超临界流体静态染色的装置,由于在显色固色过程中,超临界流体处于静止状态,省去了复杂的超临界流体循环流动设备,整个系统设备更为简单,使得设备的投入和能量消耗大大减小。
由于显色固色过程超临界流体处于静止状态,不会发生染料迁移现象,染色质量直接取决于上染质量,从而解决了在高压超临界流体系统中染色质量不易控制的困难。
同时,由于超临界流体处于静止状态,在显色固色过程中,染料不会发生迁移现象,显色固色系统的超临界流体显色固色釜及管道内没有染料污染,所以在更换染色颜色时,不必清洗染色系统。
同时,超临界流体静态显色固色系统中可以配置多个超临界流体显色固色釜,实现多个显色固色釜循环工作,使得染色生产能够不间断地进行,极大地提高了生产效率,完全满足印染工业规模化生产的需求。
附图说明
[0023]图1为本实用新型所述采用超临界流体静态染色装置的一种实施例的结构示意图。
[0024]图2为图1所示采用超临界流体静态染色装置中上染系统的一种实施例的结构示意图。
[0025] 图3为图1所示采用超临界流体静态染色装置中超临界流体静态显色固色系统的一种实施例的结构示意图。
[0026] 图4为图3所示超临界流体静态染色固色系统中超临界流体显色固色釜的一种实施例的结构示意图。
[0027] 图1中,100为上染系统,200为超临界流体静态染色显色固色系统,101为上染装置,102为染料池,201为超临界流体供应装置,202为超临界流体显色固色爸,203为超临界流体回收装置。
[0028] 图2中,110为导向辊,112为一级轧辊,114为一级浸液槽,116为二级轧辊,118为二级浸液槽,120为染液罐,122为染液泵,130为未上染胚布卷,132为上染后胚布卷。
[0029] 图3中,210为I号超临界流体显色固色釜,212为2号超临界流体显色固色釜,220为二氧化碳储罐,222为二氧化碳压缩机,224为二氧化碳加热器,230为二氧化碳回收储罐,HI为加热介质出口,HO为加热介质出口,VfV9为阀门。
[0030] 图4中,211为釜体,213为釜盖密封装置,214为待染物固定装置,215为超临界流体进口,216为超临界流体出口,218为保温夹套,240为待染物,HI为加热介质出口,HO为加热介质出口。
具体实施方式
[0031] 为更好的说明本实用新型的目的、技术方案和优点,下面结合附图和具体实施例对本实用新型作进一步说明。
[0032] 本实用新型提供了一种采用超临界流体静态染色的装置,如附图1、2和3所示的所述采用超临界流体静态染色的装置的一种实施例的结构示意图,包括上染系统100和超临界流体静态显色固色系统200,所述上染系统100包括上染装置101及与所述上染装置101连接的染料池102;所述超临界流体静态显色固色系统200包括超临界流体供应装置201、与所述超临界流体供应装置201连接的一台或一台以上并联的超临界流体显色固色釜202、与所述超临界流体显色固色釜202连接的超临界流体回收装置203。
[0033] 所述上染系统100用于纤维、纱线和织物等待染物的染料上染,在这一系统中,根据纤维、纱线和织物的不同,将染料在常压、常温状态下采用浸泡、喷涂、浸轧、转移等方式均匀地上染于纤维、纱线和织物,需控制纤维、纱线和织物的带液率为(T90%。
[0034] 如附图3所示,所述超临界流体静态显色固色系统200,用于上染后的纤维、纱线和织物的显色和固色。
所述超临界流体供应装置201,用于向所述超临界流体显色固色釜202提供超临界流体,根据选用工作流体的不同,所述超临界流体供应装置201的配置也不同,但一般情况需配置流体储罐220、与所述流体储罐220连接的流体加压设备222以及加热或冷却设备224,所述加压设备222用于实现超临界流体染色工艺条件,所述流体加压设备222可采用压缩机或高压泵等,所述加热或冷却设备224可采用换热器。
[0035] 所述超临界流体静态显色固色系统200中的超临界流体显色固色釜202为该染色系统的核心部分,如附图4所示,所述超临界流体显色固色釜202包括釜体211、设于釜体211上部的快开式的釜盖密封装置213、内置于釜体211中的待染物固定装置214、设于釜体211上的超临界流体进口215和超临界流体出口216以及用于保持釜体211恒定的温度的保温夹套218。
使用时,将待染物240置于釜体211中的待染物固定装置214进行固定,超临界流体通过超临界流体进口215进入到釜体211中,加热介质通过加热介质入口HI进入保温夹套218以保持釜体211的恒定的温度,超临界流体在釜体211中静态对待染物240进行显色固色;显色固色结束后,通过超临界流体出口216将超临界流体排出,通过加热介质出口HO将加热介质排出,然后打开釜盖密封装置213,取出显色固色后的待染物240即可。
[0036] 如附图3所示,所述超临界流体回收装置203,一般设置为超临界流体回收储罐230以及连接于超临界流体显色固色釜(210、212)之间的减压阀门和管路。
回收于超临界流体回收储罐(230)中的超临界流体经过加压升温后可以重复使用。
[0037] 较佳地,所述超临界流体静态显色固色系统200还包括电气仪表控制系统(图1中未画出),所述电气仪表控制系统对系统工作状态下超临界流体的压力、温度、流量、液位等参数进行控制和记录,使得操作人员通过调整工艺参数以控制染色的质量和产量。
[0038] 采用上述所述超临界流体静态染色装置对待染物进行静态染色时,可采用以下步骤:
[0039] (I)上染:将待染物置于上染系统100的上染装置101,将染料池102中的染料加入到上染装置101中,对待染物进行上染;
[0040] (2)超临界流体静态显色固色:将步骤(I)中上染后的待染物放入超临界流体显色固色釜202中,从超临界流体供应装置201输出超临界流体至超临界流体显色固色釜202,在超临界流体显色固色釜202中,将待染物在静态超临界流体中进行显色及固色;
[0041] (3)显色及固色结束后,排除系统压力,回收超临界流体到超临界流体回收装置203中,打开超临界流体显色固色釜202,取出待染物即可。
[0042] 较佳地,步骤(I)中,根据待染物的不同,染料在常压、常温状态下采用浸泡、喷涂、浸轧或转移的方式使染料上染。
所述待染物经过步骤(I)的上染过程后带液率为犷90%。
所述步骤(I)中采用染料选自直接染料、酸性染料、活性染料、阳离子染料、分散染料、还原染料、偶氮染料、硫化染料以及不含助剂的染料原粉中的至少一种。
[0043] 较佳地,所述步骤(2)中的超临界流体选自水、氮气、二氧化碳、乙烷、乙烯、丙烷、丙烯、氨、甲醇、乙醇中的至少一种。
所述步骤(2)中待染物在超临界流体显色固色釜中静态染色的压力为l〜60MPa,温度为0〜220°C。
所述步骤(2)中,在超临界流体显色固色釜中,待染物在静态超临界流体中进行显色及固色的时间为0.5^5小时。
[0044] 上述所述待染物一般为纤维、纱线或织物。
所述纤维包括天然纤维、合成纤维及混纺纤维。
[0045] 以下以涤纶针织胚布采用本实用新型一种实施例的超临界流体静态染色装置进行静态染色过程为例,进一步对本实用新型进行说明。
[0046] 本实施例中采用的超临界流体为二氧化碳。
[0047] 一、涤纶针织胚布织物的上染过程
[0048] 如附图1和2所示的一种实施例的上染系统的结构示意图,所述上染装置101包括与未上染胚布卷130连接的导向辊110,与导向辊110依次连接的一级浸液槽114、一级轧辊112和二级浸液槽118、二级轧辊116,与所述二级轧辊116连接的上染后胚布卷132;所述染料池102包括染液罐120和染液泵122;所述一级浸液槽114和二级浸液槽118与染液罐120连接,所述染液罐120中的染液通过染液泵122输送到一级浸液槽114和二级浸液槽118中。
[0049] 采用如上所述的上染系统对待染物上染时,首先,根据产品颜色在专用的小样机上进行打小样调色,得到生产用染液的配方;然后根据配方选择燃料并依据待染物质量及待染物的带液率一次性配置染液;
[0050] 将配好的染液加入带搅拌的染液罐120中,然后用可调节流量的染液泵122把染液送入一级浸液槽114和二级浸液槽118;
[0051] 未上染涤纶针织胚布卷130经导向辊110将胚布送入一级浸液槽114浸液,然后进入一级轧辊112进行轧液,再依次进入二级浸液槽118和二级轧辊116进行二次浸液和轧液,要求待染物的带液率控制在0〜90%,二次轧液后的待染物上染完成,得上染后胚布卷132。
[0052] 二、超临界二氧化碳静态显色固色过程
[0053] 如附图1和3所示的一种实施例的超临界流体静态显色固色系统的结构示意图,所述超临界流体静态显色固色系统包括超临界流体供应装置201,与所述超临界流体供应装置201连接的两台并联的超临界流体显色固色釜(210、212)、与所述超临界流体显色固色釜(210、212)连接的超临界流体回收装置203。
所述超临界流体供应装置201包括二氧化碳储罐220、用于实现超临界二氧化碳染色工艺条件的二氧化碳压缩机222以及二氧化碳加热器224。
所述超临界流体回收装置203为二氧化碳回收储罐230。
[0054] 采用如上所述的超临界流体静态显色固色系统对待染物进行静态显色固色时,操作步骤如下:
[0055]1、首先将经过上述上染过程处理过的上染后胚布卷132放入其中一个超临界流体显色固色釜(210或212)中,关闭釜盖备用;
[0056] 2、然后开通加热装置,使加热介质连续供应到二氧化碳加热器224、超临界流体显色固色釜(210、212),分别使其达到预先设定的温度;打开阀门V9,使二氧化碳储罐220中的二氧化碳进入二氧化碳回收罐230备用;
[0057] 3、打开阀门V8,启动二氧化碳压缩机222,使来自二氧化碳回收储罐230的二氧化碳升压到临界压力7.1MPa以上且满足工艺要求的超临界状态压力,范围一般为8〜70MPa;
[0058] 4、来自二氧化碳压缩机222的二氧化碳进入二氧化碳加热器224进行加热,使二氧化碳的温度达到其临界温度32°C以上且满足工艺要求的超临界状态温度,范围一般为35^2000C,经加压升温后的二氧化碳成为超临界二氧化碳;
[0059] 5、打开阀门VI,使超临界二氧化碳进入超临界流体显色固色釜(210、212)中,使釜内二氧化碳达到满足工艺要求的超临界状态;
[0060] 6、关闭阀门VI,保持一定时间,范围一般是0.5^5小时,使得上染于胚布的染料在静止超临界二氧化碳状态下显色及固色;
[0061] 7、显色固色完毕,缓慢打开阀门V3和V7,使超临界流体显色固色釜(210、212)内的二氧化碳缓慢进入二氧化碳回收储罐230中备用;
[0062] 8、打开阀门V2,排空超临界流体显色固色釜(210、212)中的二氧化碳,打开釜盖,取出染色后的涤纶布卷。
[0063] 最后所应当说明的是,以上实施例仅用以说明本实用新型的技术方案而非对本实用新型保护范围的限制,尽管参照较佳实施例对本实用新型作了详细说明,本领域的普通技术人员应当理解,可以对本实用新型的技术方案进行修改或者等同替换,而不脱离本实用新型技术方案的实质和范围。
Claims(5)
1. 一种采用超临界流体静态染色方法的装置,其特征在于,所述装置包括上染系统和超临界流体静态显色固色系统;所述上染系统包括上染装置及与所述上染装置连接的染料池;所述超临界流体静态显色固色系统包括超临界流体供应装置、与所述超临界流体供应装置连接的一台或一台以上并联的超临界流体显色固色釜、与所述超临界流体显色固色釜连接的超临界流体回收装置。
2.如权利要求1所述的采用超临界流体静态染色的装置,其特征在于,所述超临界流体供应装置包括流体储罐、与所述流体储罐连接的流体加压设备及加热或冷却设备。
3.如权利要求2所述的采用超临界流体静态染色的装置,其特征在于,所述流体加压设备为压缩机或高压泵;所述加热或冷却设备为换热器。
4.如权利要求1所述的采用超临界流体静态染色的装置,其特征在于,所述超临界流体显色固色釜包括釜体、设于釜体上部的釜盖密封装置、内置于釜体中的待染物固定装置、设于釜体上的超临界流体进口和超临界流体出口以及用于保持釜体温度的保温夹套。
5.如权利要求1所述的采用超临界流体静态染色装置,其特征在于,所述装置还包括用于对超临界流体的压力、温度、流量和液位进行控制和记录的电气仪表控制系统。
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广东出色无水印染科技有限公司
一种采用超临界流体静态染色的方法和装置
CN108867116A
(zh)
*
2018-04-27
2018-11-23
青岛即发集团股份有限公司
一种超临界co2染色方法及染色系统
CN109235079A
(zh)
*
2018-08-14
2019-01-18
青岛即发集团股份有限公司
一种超临界co2棉及棉混纺织物染色方法
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2012-09-04
2012-12-12
广东出色无水印染科技有限公司
一种采用超临界流体静态染色的方法和装置
CN108867116A
(zh)
*
2018-04-27
2018-11-23
青岛即发集团股份有限公司
一种超临界co2染色方法及染色系统
CN109235079A
(zh)
*
2018-08-14
2019-01-18
青岛即发集团股份有限公司
一种超临界co2棉及棉混纺织物染色方法
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